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中文名 | 氯(五甲基环戊二烯)(环辛二烯)钌(II) |
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英文名 | Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium |
中文别名 |
(1,5-环辛二烯)(五甲基环戊二烯)氯化铷
氯(五甲基环戊二烯基)(环辛二烯)钌(II) (1,5-环辛二烯)(五甲基环戊二烯基)氯化钌(II) |
英文别名 |
Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II)
1,5-Cyclooctadiene MFCD07369035 |
分子式 | C18H27ClRu |
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分子量 | 379.93000 |
精确质量 | 380.08400 |
LogP | 6.33430 |
储存条件 | 密闭于阴凉干燥环境中 |
稳定性 | 遵照规定使用和储存则不会分解。 |
分子结构 | 1、摩尔折射率:无可用 2、 摩尔体积(cm3/mol):无可用 3、 等张比容(90.2K):无可用 4、 表面张力(dyne/cm):无可用 5、 极化率:无可用 |
计算化学 | 1.疏水参数计算参考值(XlogP):无 2.氢键供体数量:0 3.氢键受体数量:1 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积0 7.重原子数量:20 8.表面电荷:0 9.复杂度:147 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:2 14.不确定化学键立构中心数量:0 15.共价键单元数量:3 |
更多 | 1. 性状:无可用 2. 密度(g/mL,25/4℃):无可用 3. 相对蒸汽密度(g/mL,空气=1):无可用 4. 熔点(ºC):无可用 5. 沸点(ºC,常压):无可用 6. 沸点(ºC,5.2kPa):无可用 7. 折射率:无可用 8. 闪点(ºC):无可用 9. 比旋光度(º):无可用 10. 自燃点或引燃温度(ºC):无可用 11. 蒸气压(kPa,25ºC):无可用 12. 饱和蒸气压(kPa,60ºC):无可用 13. 燃烧热(KJ/mol):无可用 14. 临界温度(ºC):无可用 15. 临界压力(KPa):无可用 16. 油水(辛醇/水)分配系数的对数值:无可用 17. 爆炸上限(%,V/V):无可用 18. 爆炸下限(%,V/V):无可用 19. 溶解性:无可用 |
Section 1: Product Identification Chemical Name:Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium (II), 98% CAS Registry Number:92390-26-6 Formula:RuCl(C8H12)(C10H15) EINECS Number:none Chemical Family:organometallic complex Synonym:Chloro(pentamethylcyclopentadienyl)(1,5-cyclooctadiene)ruthenium
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound92390-26-6100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed. Primary Routes of Exposure:Ingestion, inhalation, skin, eyes Eye Contact:Causes irritation of the eyes. Skin Contact:Causes irritation of the skin. Inhalation:Dust is irritating to the nose, mucous membranes and respiratory tract. Ingestion:No specific information is available on the physiological effects of ingestion. May be harmful if swallowed. Acute Health Affects:Irritating to skin, eyes and respiratory tract. May be harmful if swallowed. Chronic Health Affects:No information on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:none Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, dry powder or foam If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire, this material may emit toxic fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Handling and Storage:Store cold, in a tightly sealed container. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:brown microcrystals Molecular Weight:379.93 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:not determined Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable (store cold) Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:oxidizing agents, halogens and active metals. Decomposition Products:carbon monoxide, carbon dioxide, organic fumes, phosphorous pentoxide and ruthenium oxide. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory SARA (Title 313):Title compound not listed Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
生态学数据: 该物质对环境可能有:,对水体应给予特别注意。
|
符号 |
GHS02 |
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信号词 | Danger |
:ι | H261 |
警示性声明 | P231 + P232-P422 |
个人防护装备 | Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges |
:β (欧洲) | Xi |
风险声明 (欧洲) | 20/21/22 |
安全声明 (欧洲) | 22-36/37/39 |
危险品运输编码 | UN 3395 |
~92% 92390-26-6 |
文献:Fagan, Paul J.; Mahoney, Wayne S.; Calabrese, Joseph C.; Williams, Ian D. Organometallics, 1990 , vol. 9, p. 1843 - 1852 |
~77% 92390-26-6 |
文献:Bosch, H. William; Hund, Hans-Ulrich; Nietlispach, Daniel; Salzer, Albrecht Organometallics, 1992 , vol. 11, p. 2087 - 2098 |
~% 92390-26-6 |
文献:Chemistry Letters, , p. 1161 - 1164 |
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